Aziridination of alkenes and amidation of alkanes by bis (tosylimido) ruthenium (vi) porphyrins. A mechanistic study

…, JS Huang, WY Yu, WH Fung, CM Che

文献索引：Au, Sze-Man; Huang, Jie-Sheng; Yu, Wing-Yiu; Fung, Wai-Hong; Che, Chi-Ming Journal of the American Chemical Society, 1999 , vol. 121, # 39 p. 9120 - 9132

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被引用次数: 238

摘要

Bis (tosylimido) ruthenium (VI) porphyrins,[RuVI (Por)(NTs) 2](Por= TPP, TTP, 4-Cl-TPP, 4- MeO-TPP, OEP), were prepared in 60-74% yields by treatment of [RuII (Por)(CO)(MeOH)] with (N-(p-tolylsulfonyl) imino) phenyliodinane (PhI NTs) in dichloromethane. In dichloromethane containing pyrazole, they reacted with alkenes or alkanes to give tosylamidoruthenium (IV) porphyrins,[RuIV (Por)(NHTs)(pz)], in about 75% yields. The ...