Hydrosilylation of olefins in the presence of metal carbonyls

GKI Magomedov, KA Andrianov, OV Shkolnik…

文献索引：Magomedov,G.K.I. et al. Journal of Organometallic Chemistry, 1978 , vol. 149, p. 29 - 36

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被引用次数: 10

摘要

Abstract Hydrosilylation of cardinal types of olefins, R′ CH CH 2 (R′= C 3 H 7 C 10 H 21, C 6 H 5, Si (CH 3) 3, CH 2 N (CH 3) 2, CH 2 N [Si (OC 2 H 5) 3] 2 and cyclopentadiene with silanes, HSiR ″n X 3− n (n= 1 or 2, R ″= CH 3 or C 2 H 5, X= Cl; n= O, X= Cl, OC 2 H 5) in the presence of the catalytic metal carbonyls Co 2 (CO) 8, and Rh 4 (CO) 12, is described Alkylchloro (ethoxy) silanes, R′ CH 2 CH 2 SiR ″n X 3− n and ...