Mechanistic insights into the hydrosilylation of allyl compounds–Evidence for different coexisting reaction pathways
…, M Drees, K Riener, B Bechlars, WA Herrmann…
文献索引：Gigler, Peter; Drees, Markus; Riener, Korbinian; Bechlars, Bettina; Herrmann, Wolfgang A.; Kuehn, Fritz E. Journal of Catalysis, 2012 , vol. 295, p. 1 - 14
The hydrosilylation of allyl compounds is often accompanied by the formation of high amounts of byproducts. The formation processes have not been fully understood so far. In this work, the allyl hydrosilylation mechanism is investigated in detail and experimental and theoretical evidence for multiple, coexisting reaction pathways is provided. Based on earlier reports and the observations during an extensive catalytic study, different pathways, ...
