Chemistry of dioxiranes. 13. Oxidation of primary amines by dimethyldioxirane

RW Murray, SN Rajadhyaksha…

文献索引：Murray, Robert W.; Rajadhyaksha, Shirish N.; Mohan, Lily Journal of Organic Chemistry, 1989 , vol. 54, # 24 p. 5783 - 5788

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被引用次数: 87

摘要

Many nitro compounds are difficult to synthesize by direct nitration methods. However, some success has been achieved by direct oxidation of the corresponding amines using either peracids or hydrogen peroxidea2* We earlier reported'that dimethyldioxirane (1) oxidizes some primary amines to nitro compounds. We have now followed up our earlier work by oxidizing a variety of primary amines to the corresponding nitro compounds through the ...