Journal of fluorine chemistry

Generation and thermal polymerization of 1-fluoro-2-phenylacetylene

T Okano, K Ito, T Ueda, H Muramatsu

文献索引：Okano,T.; Ito,K.; Ueda,T. Journal of Fluorine Chemistry, 1986 , vol. 32, p. 377

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被引用次数: 22

摘要

Abstract Some routes to the synthesis of 1-fluoro-2-phenylacetylene were attempted. Although the halogen exchange of chloro-and bromophenylacetylenes and dehydrobromination of dibromofluorophenylacetylene were unsuccessful, defluorosilylation of 1, 1-difluoro-2-phenyl-2-trimethylsilylethene (which was prepared by lithiation of bromodifluorovinylbenzene followed by silylation with chlorotrimethylsilane) with CsF ...