The Journal of Physical Chemistry

Stereodynamics of N-Ethyl-N-methyl-2-aminopropane. 1H and 13C {1H} DNMR Studies. Molecular Mechanics Calculations

JH Brown, CH Bushweller

文献索引：Brown, Jay H.; Bushweller, C. Hackett Journal of Physical Chemistry, 1994 , vol. 98, # 44 p. 11411 - 11419

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被引用次数: 10

摘要

N-Ethyl-N-methyl-2-aminopropane (EMAP) is one of the simplest tertiary aliphatic amines that has a chiral center at nitrogen. Racemization occurs by inversion-rotation at the pyramidal nitrogen. For each EMAP enantiomer, additional conformational interconversions