Palladium-iminophosphine-catalyzed alkynylstannylation of alkynes

…, E Shirakawa, T Kurahashi, Y Nakao, T Hiyama

文献索引：Shirakawa, Eiji; Murota, Yasubumi; Nakao, Yoshiaki; Hiyama, Tamejiro Synlett, 1997 , vol. 1997, # 10 p. 1143 - 1144

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被引用次数: 58

摘要

A palladium complex coordinated by an iminophosphine ligand was found to catalyze the addition of alkynylstannanes to a carbon−carbon triple bond of various alkynes in moderate to good yields with exclusive syn selectivity. The alkynyl group in the stannanes was attached mainly to the