Preparation, structure, and properties of pseudotetrahedral, D2d complexes of copper (II), nickel (II), cobalt (II), copper (I), and zinc (II) with the geometrically …

S Knapp, TP Keenan, X Zhang, R Fikar…

文献索引：Knapp; Keenan; Zhang; Fikar; Potenza; Schugar Journal of the American Chemical Society, 1990 , vol. 112, # 9 p. 3452 - 3464

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被引用次数: 108

摘要

Abstract: The bidentate ligand 2, 2'-bis (2-imidazolyl) biphenyl (3= L) has been synthesized and used to prepare perchlorate complexes containing Cu (I1)(S), Ni (l1)(6), Co (I1)(7), Cu (I)(8), and Zn (I1). X-ray structure analysis of 5-8 reveals pseudotetrahedral, MN (imH) 4 chromophores, each with approximate Du point symmetry. The ligand 3 exerts an unprecedented degree of geometric control of the coordination spheres for complexes of ...