Simultaneous and stereoselective construction of planar and axial centers of chirality

L Fogel, RP Hsung, WD Wulff…

文献索引：Fogel; Hsung; Wulff Journal of the American Chemical Society, 2001 , vol. 123, # 23 p. 5580 - 5581

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被引用次数: 34

摘要

Atropisomerism resulting from hindered rotation about single bonds can lead to molecules with centers of axial chirality and are widely used in asymmetric catalytic synthesis. 1 Molecules containing planar centers of chirality have also been used as chiral ligands, particularly those containing η6-benzene and η5-cyclopentadienyl complexes. 2 To our knowledge, there are no known synthetic methods that produce both types of chiral ...