(Trimethylsilyl) cyclopentene annulation: a regiocontrolled approach to the synthesis of five-membered rings

RL Danheiser, DJ Carini, A Basak

文献索引：Danheiser, Rick L.; Carini, David J.; Basak, Ajoy Journal of the American Chemical Society, 1981 , vol. 103, # 6 p. 1604 - 1606

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被引用次数: 131

摘要

The identification of the prostaglandins and polyquinane natural products as important synthetic targets has stimplated the development of an impressive methodology for the synthesis of five-membered carbocycles. In this communication we describe a new and conceptually novel [3+ 21 approach to cyclopentane derivatives: the (trimethylsi1yl) cyclopentene annulation. A unique feature of this one-step annulation is its capacity to ...