Exocyclic Substitution of Five-Membered Ring Chlorophosphates: A Reexamination of the rule For Nucleophilic Substitution at Phosphorus

RJP Corriu, GF Lanneau, D Leclercq

文献索引：Corriu, R. J. P.; Lanneau, G. F.; Leclercq, D. Phosphorus and Sulfur and the Related Elements, 1983 , vol. 18, p. 197 - 200

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被引用次数: 8

摘要

Abstract Opposite to the SN2 (P) reactions taking place with inversion, which are highly dependent upon the nature of the nucleophile, exocyclic substitutions of five-membered ring chlorophosphates with retention show a marked kinetic levelling effect, emphasing silicon- type argumentations.