Tetrahedron Letters

Synthesis of homoallyl alcohols by the reaction of π-allyldicyclopentadienyltitanium (III) with carbonyl compounds

F Sato, S Iijima, M Sato

文献索引：Sato, Fumie; Iijima, Satoshi; Sato, Masao Tetrahedron Letters, 1981 , vol. 22, p. 243 - 246

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被引用次数: 73

摘要

Abstract Reaction of π-allyldicyclopentadienyititanium (III) complexes, preformed or formed in situ, with aldehydes or ketones proceeds with regiospecificity, high stereoselectivity and chemospecificity, affording, under mild conditions, the corresponding homoallyl alcohols after hydrolysis in excellent yields.