The Journal of Organic Chemistry

Mixed methyl-silyl ketals of quinones. Their preparation via anodic oxidation and their chemistry

A Stern, JS Swenton

文献索引：Stern, Alan; Swenton, John S. Journal of Organic Chemistry, 1987 , vol. 52, # 13 p. 2763 - 2768

全文：HTML全文

被引用次数: 26

摘要

Quinone bisketals are protected quinone derivatives' which are readily converted to synthetically versatile quinone monoketals2 by acid hydrolysis. However, for preparation of highly reactive and/or acid-labile quinone derivatives (eg, quinone imines3), a carbonyl protecting group which could be deblocked under mild, neutral conditions in nonnucleophilic media is desirable (Scheme I). One candidate for such a carbonyl ...