Tetrahedron

Synthesis and chemical diversity analysis of bicyclo [3.3. 1] non-3-en-2-ones

…, J Contreras-García, AM Virshup, DN Beratan, W Yang…

文献索引：Hammill, Jared T.; Contreras-Garcia, Julia; Virshup, Aaron M.; Beratan, David N.; Yang, Weitao; Wipf, Peter Tetrahedron, 2010 , vol. 66, # 31 p. 5852 - 5862

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被引用次数: 4

摘要

Functionalized bicyclo [3.3. 1] non-3-en-2-ones are obtained from commercially available phenols by a hypervalent iodine oxidation, enone epoxidation, epoxide thiolysis, and intramolecular aldol reaction sequence. Reaction optimization studies identified room temperature as well as microwave-mediated procedures, providing moderate to good yields (57–88%) in the thiophenol-mediated epoxide opening and intramolecular aldol reaction. ...

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Oxidation of hydroquinone silyl ethers to quinones

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[Pelter, Andrew; Elgendy, Said Tetrahedron Letters, 1988 , vol. 29, # 6 p. 677 - 680]

Asymmetric synthesis of functionalized 1, 2, 3, 4-tetrahydro...

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