Journal of Chemical Crystallography

Synthesis, Crystal Structures and Fluorescence Properties of Ni (II) and Cu (II) Complexes with 1-(Furan-2-ylmethylene)-4-phenylthiosemicarbazone

PP Sun, FF Jian, X Wang

文献索引：Sun, Ping Ping; Jian, Fang Fang; Wang, Xian Journal of Chemical Crystallography, 2010 , vol. 40, # 1 p. 4 - 9

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被引用次数: 6

摘要

Abstract Two coordination complexes, NiL 2 and CuL 2 {L= bis [1-(furan-2-ylmethylene)-4- phenylthiosemicarbazone]}, were synthesized and determined by X-ray crystallography. Both crystallize in the Orthorhombic system, space group Pbcn, with lattice parameters: a= 11.935 (2) Å, b= 15.314 (3) Å, c= 12.952 (3) Å and Z= 4 for Ni (II); a= 20.850 (4) Å, b= 15.049 (3) Å, c= 7.5633 (5) Å and Z= 4 for Cu (II). In both complexes, the central metal atom is ...