Regioselectivity of the Rhodium??Catalyzed Hydroboration of Vinyl Arenes: Electronic Twists and Mechanistic Shifts

…, CJ Lata, LA Calhoun, CM Crudden

文献索引：Edwards, David R.; Hleba, Yonek B.; Lata, Christopher J.; Calhoun, Larry A.; Crudden, Cathleen M. Angewandte Chemie - International Edition, 2007 , vol. 46, # 41 p. 7799 - 7802

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被引用次数: 35

摘要

The hydroboration of alkenes represents a versatile synthetic method for the functionalization of organic compounds.[1] The installed carbon–boron bond can be converted into CÀO, CÀ N, and CÀC bonds with retention of stereochemistry.[1b] Several highly enantioselective catalysts have been developed by the groups of Hayashi,[2] Brown,[3] Knochel,[4] Togni,[5] and Takacs [6] among others, allowing the hydroboration ...