tert-Butoxide-mediated arylation of benzene with aryl halides in the presence of a catalytic 1, 10-phenanthroline derivative

E Shirakawa, K Itoh, T Higashino…

文献索引：Shirakawa, Eiji; Itoh, Ken-Ichi; Higashino, Tomohiro; Hayashi, Tamio Journal of the American Chemical Society, 2010 , vol. 132, # 44 p. 15537 - 15539

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被引用次数: 280

摘要

Sodium tert-butoxide mediates the coupling of aryl halides with benzene derivatives without the aid of transition metal catalysts but with a catalytic 1,10-phenanthroline derivative. ... The reaction was carried out under a nitrogen atmosphere using 4-iodotoluene (1a: 0.225 mmol) and benzene (2a: 2.4 mL, 27 mmol) in a sealed tube. ... The reaction was carried out under a nitrogen atmosphere using an aryl halide (1: 0.225 mmol), an arene (2: 27 mmol), ...

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