Tetrahedron Letters

A convenient procedure for smooth palladium-catalyzed allylic alkylation by sodium dimethyl malonate and cyclopentadienide. A new synthesis of allylic substituted …

JC Fiaud, JL Malleron

文献索引：Fiaud, J. C.; Malleron, J. L. Tetrahedron Letters, 1980 , vol. 21, p. 4437 - 4440

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被引用次数: 41

摘要

Abstract The use of the Pd (dba) 1 2/dpe catalytic system in allylic alkylation allows sodium dimethyl malonate to react with allylic acetates at room temperature. According to this procedure, a novel synthesis of allylic substituted cyclopentadienes is described through the use of cyclopentadienide anion as a nucleophile.