Tetrahedron letters

Regio-and stereodefined synthesis of trimethylsilyl enol ethers resulted from the isomerization of α-trimethylsilyl ketones

I Matsuda, S Sato, M Hattori, Y Izumi

文献索引：Matsuda, Isamu; Sato, Susumu; Hattori, Motoaki; Izumi, Yusuke Tetrahedron Letters, 1985 , vol. 26, # 27 p. 3215 - 3218

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被引用次数: 20

摘要

Abstract The isomerization of an α-trimethylsilyl ketone is lead to the corresponding trimethylsilyl enol ether with the enhanced regioselectivity by heating or by the assist of trimethylsilyl trifluoromethanesulfonate. The thermal reaction discloses a new regiodefined (E)-selective route to silyl enol ethers.