Chemical Communications

A stereoselective isomerization of allyl silyl ethers to (E)-or (Z)-silyl enol ethers using cationic iridium complexes

T Ohmura, Y Yamamoto, N Miyaura

文献索引：Ohmura, Toshimichi; Shirai, Yasuo; Yamamoto, Yasunori; Miyaura, Norio Chemical Communications, 1998 , # 13 p. 1337 - 1338

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被引用次数: 20

摘要

OSiR3 3 R1 OSiR3 3 R2 R1 ... 1a R3 3Si = TMS b R3 3Si = TBDMS ... 2 = [Ir(cod)(PMePh2)2 ]PF6/(H2 or catecholborane) 3 = [Ir(cod)2]PF6–2R3P/H2 ... A stereoselective isomerization of allyl silyl ethers to (E)- or (Z)-silyl enol ethers using cationic iridium complexes ... Toshimichi Ohmura,Yasuo Shirai, Yasunori Yamamoto and Norio Miyaura*† Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, ...