Journal of the American Chemical Society

Silicon-promoted Nef reaction by a. gamma.-effect

JR Hwu, BA Gilbert

文献索引：Hwu, Jih Ru; Gilbert, Bryant A. Journal of the American Chemical Society, 1991 , vol. 113, # 15 p. 5917 - 5918

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被引用次数: 38

摘要

We have described a versatile protecting group (TBDMS) for 1 ,2-C2BloHI2 that allows the efficient synthesis of monosubstituted and linked carboranes. The generality of the method coupled with the high yields obtained offers a valuable new tool for organic transformations on carborane cages. As shown previously, the silyl substituent on carborane cages provides unique reactivity, crystal growth and cage stability.* Work that extends to other areas of carborane ...