Synthesis

Silicon-catalyzed conversion of nitro compounds into ketones and poly (1, 3-diketones)

JR Hwu, T Josephrajan, SC Tsay

文献索引：Hwu, Jih Ru; Josephrajan, Thainashmuthu; Tsay, Shwu-Chen Synthesis, 2006 , # 19 p. 3305 - 3308

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被引用次数: 4

摘要

Abstract The reaction of various secondary nitro compounds with 1.1 equivalents of potassium hydride in 1, 4-dioxane and then with 0.10 equivalent of chlorotrimethylsilane gave the corresponding ketones in 62-90% yields. By a similar strategy, poly (1, 3- diketones) were synthesized directly from nitroalkenes with sodium ethoxide, potassium hydride, and chlorotrimethylsilane in 1, 4-dioxane. The use of chlorotrimethylsilane in a ...