Organic Letters

Palladium-catalyzed cross-coupling reactions of triorganoindium compounds with vinyl and aryl triflates or iodides

I Pérez, JP Sestelo, LA Sarandeses

文献索引：Perez, Ignacio; Sestelo, Jose Perez; Sarandeses, Luis A. Organic Letters, 1999 , vol. 1, # 8 p. 1267 - 1269

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被引用次数: 136

摘要

A novel palladium-catalyzed cross-coupling reaction of organoindium compounds with vinyl and aryl triflates or iodides is described. The reaction proceeds for alkyl-, vinyl-, alkynyl-, and arylindium compounds in excellent yields and high chemoselectivity without any excess of the organometallic. Remarkably, indium organometallics transfer efficiently the three organic groups attached to the metal.