Reaction of Xenon Difluoride. Part II. Oxidative-fluorination of Phosphorus and Iodine Compounds and Cleavage of Silicon-Sulfur and Silicon-Nitrogen Bonds

JA Gibson, RK Marat…

文献索引：Gibson,J.A. et al. Canadian Journal of Chemistry, 1975 , vol. 53, p. 3044 - 3052

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被引用次数: 31

摘要

Reaction of alkyl (aryl) phosphines with xenon difluoride gives alkyl (aryl) hydridofluorophosphoranes which were characterized by proton and fluorine nmr spectroscopy. With phenylchlorophosphines, substitution of chlorine by fluorine accompanied oxidative-fluorination to give phenylfluorophosphoranes,(C6H5) n PF5-n. With tert-butylchlorophosphines, chlorination of the tert-butyl group accompanied oxidative- ...