Reaction of Xenon Difluoride. Part II. Oxidative-fluorination of Phosphorus and Iodine Compounds and Cleavage of Silicon-Sulfur and Silicon-Nitrogen Bonds

JA Gibson, RK Marat…

Index: Gibson,J.A. et al. Canadian Journal of Chemistry, 1975 , vol. 53, p. 3044 - 3052

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Citation Number: 31

Abstract

Reaction of alkyl (aryl) phosphines with xenon difluoride gives alkyl (aryl) hydridofluorophosphoranes which were characterized by proton and fluorine nmr spectroscopy. With phenylchlorophosphines, substitution of chlorine by fluorine accompanied oxidative-fluorination to give phenylfluorophosphoranes,(C6H5) n PF5-n. With tert-butylchlorophosphines, chlorination of the tert-butyl group accompanied oxidative- ...