The Journal of Physical Chemistry A

Reactions of Mn (II) and Mn (III) with alkyl, peroxyalkyl, and peroxyacyl radicals in water and acetic acid

JE Jee, A Bakac

文献索引：Jee, Joo-Eun; Bakac, Andreja Journal of Physical Chemistry A, 2010 , vol. 114, # 5 p. 2136 - 2141

全文：HTML全文

被引用次数: 5

摘要

The kinetics of oxidation of Mn (II) with acylperoxyl and alkylperoxyl radicals were determined by laser flash photolysis utilizing a macrocyclic nickel complex as a kinetic probe. Radicals were generated photochemically from the appropriate ketones in the