Aliphatic C− H Bond Activation Initiated by a (μ-η2: η2-Peroxo) dicopper (II) Complex in Comparison with Cumylperoxyl Radical

…, H Furutachi, S Fujinami, S Fukuzumi…

文献索引：Matsumoto, Takahiro; Ohkubo, Kei; Honda, Kaoru; Yazawa, Akiko; Furutachi, Hideki; Fujinami, Shuhei; Fukuzumi, Shunichi; Suzuki, Masatatsu Journal of the American Chemical Society, 2009 , vol. 131, # 26 p. 9258 - 9267

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被引用次数: 30

摘要

A (μ-η2: η2-peroxo) dicopper (II) complex,[Cu2 (HL)(O2)] 2+(1-O 2), supported by the dinucleating ligand 1, 3-bis [bis (6-methyl-2-pyridylmethyl) aminomethyl] benzene (HL) is capable of initiating C− H bond activation of a variety of external aliphatic substrates (SH n): 10-methyl-9, 10-dihydroacridine (AcrH2), 1, 4-cyclohexadiene (1, 4-CHD), 9, 10- dihydroanthracene (9, 10-DHA), fluorene, tetralin, toluene, and tetrahydrofuran (THF), ...