Solvent system ethanol-2, 2, 2-trifluoroethanol as a medium for solvolytic displacement

DA Da Roza, LJ Andrews…

文献索引：da Roza,D.A. et al. Journal of the American Chemical Society, 1973 , vol. 95, p. 7003 - 7009

全文：HTML全文

被引用次数: 22

摘要

Abstract: A comparative rate study of the solvolyses of benzyl bromide and chloride and their m-fluoro and p-methyl derivatives in various mixtures of ethanol and 2, 2, 2-trifluoroethanol has been conducted. The reactivity of p-methylbenzyl chloride increases and that of m- fluorobenzyl chloride decreases with increasing trifluoroethanol content of the medium; benzyl chloride is relatively insensitive to changes in solvent composition. These reactivity ...