The Journal of Organic Chemistry

Sterically hindered silyl perchlorates as blocking reagents

TJ Barton, CR Tully

文献索引：Barton,T.J.; Tully,C.R. Journal of Organic Chemistry, 1978 , vol. 43, p. 3649 - 3653

全文：HTML全文

被引用次数: 84

摘要

hi-tert-butylsilane, di-tert-butylmethylsilane, and tert-butyldimethylsilane were converted into the corresponding silyl perchlorates through a rapid and quantitative exchange with trityl perchlorate. Tri-tert-butylsilyl perchlorate proved somewhat difficult to prepare and was quite unreactive. tert-Butyldimethylsilyl perchlorate reacted with alcohols much more rapidly than did the usual reagent, tert-butyldimethylsilyl chloride. The ethers formed from di-tert- ...