Chemistry letters

Reduction of. ALPHA.,. BETA.-Unsaturated Ketones with Diphenylsilanes Bearing Several Substituents on Their Phenyl Moiety Catalyzed by Rhodium-Phosphine …

D Imao, M Hayama, K Ishikawa, T Ohta, Y Ito

文献索引：Imao, Daisuke; Hayama, Miyuki; Ishikawa, Kohta; Ohta, Tetsuo; Ito, Yoshihiko Chemistry Letters, 2007 , vol. 36, # 3 p. 366 - 367

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被引用次数: 4

摘要

1, 4-Addition product was afforded exclusively by rhodium–phosphine complex-catalyzed hydrosilylation by using 2-cyclohexen-1-one and a dihydrosilane bearing an ether substituent in spite of the fact that dihydrosilanes were believed to give 1, 2-addition product selectively.