Synlett

[Rh (OH)(cod)] 2 (cod= 1, 5-Cyclooctadiene): A Highly Efficient Catalyst for 1, 4-Hydrosilylation of α, β-Unsaturated Carbonyl Compounds

A Mori, T Kato

文献索引：Mori, Atsunori; Kato, Tsuyoshi Synlett, 2002 , # 7 p. 1167 - 1169

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被引用次数: 20

摘要

Abstract [Rh (OH)(cod)] 2 (cod: 1, 5-cyclooctadiene) is found to be a highly efficient catalyst for 1, 4-hydrosilylation of α, β-unsaturated carbonyl compounds leading to enolsilanes. The reaction of 2-cyclohexen-1-one with HSiMe (OEt) 2 in the presence of 0.005 mol% of the catalyst without solvent furnishes the corresponding enolsilane in 97% yield at room temperature within 10 min.