European Journal of Organic Chemistry

Visible??Light??Triggered Direct Benzoyloxylation of Electron??Rich Arenes at Room Temperature without Chelation Assistance

H Rao, P Wang, CJ Li

文献索引：Rao, Honghua; Wang, Ping; Li, Chao-Jun European Journal of Organic Chemistry, 2012 , # 33 p. 6503 - 6507

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被引用次数: 8

摘要

Abstract A Ru II photocatalytic method was developed for the direct mono-benzoyloxylation of electron-rich aromatic and heteroaromatic systems even with an excess amount of benzoyl peroxide. The reaction was conducted at room temperature under visible light. The direct Ar C–H benzoyloxylations occur without the assistance of any directing groups and can also tolerate various functional groups that have already shown diverse reactivities in ...