Journal of Organometallic Chemistry

Addition d'hydrocarbures silicies possedant une liaison Si C activee a des composes carbonyles: I. Additions au chloral

G Deleris, J Dunogues, R Calas

文献索引：Deleris,G. et al. Journal of Organometallic Chemistry, 1975 , vol. 93, p. 43 - 50

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被引用次数: 51

摘要

Abstract In the presence of a Lewis acid catalyst, silylated hydrocarbonds having an activated Si C bond (allyl-, aryl-, vinyl-, ethynyl-or propargyl-silanes) add to chloral and give after hydrolysis the corresponding α-trichloromethylated carbinols; this type of reaction is original in this series. Likewise allyltrimethylsilane adds to chloroacetone.