Advanced Synthesis & Catalysis

Synthesis of Aryl Carbamates via Copper??Catalyzed Coupling of Aryl Halides with Potassium Cyanate

X Yang, Y Zhang, D Ma

文献索引：Yang, Xinye; Zhang, Yihua; Ma, Dawei Advanced Synthesis and Catalysis, 2012 , vol. 354, # 13 p. 2443 - 2446,4

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被引用次数: 13

摘要

Stimulated by Baghersad's result, we envisioned that aryl halides might go through a similar coupling reaction, and thereby giving a more economic approach for preparing aryl carbamates. With this idea in mind, we conducted a coupling of 4-iodoanisole with potassium cyanate. It was found that under the catalysis of 20 mol% CuI and 20 mol% N,N-dimethylglycine, the reaction took place in n-BuOH at 100 °C to afford the desired ...