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VIVO Versus VIV Complex Formation by Tridentate (O, Narom, O) Ligands: Prediction of Geometry, EPR 51V Hyperfine Coupling Constants, and UV–Vis Spectra

…, K Hegetschweiler, G Micera, E Garribba

文献索引:Pisano, Luisa; Varnagy, Katalin; Timari, Sarolta; Hegetschweiler, Kaspar; Micera, Giovanni; Garribba, Eugenio Inorganic Chemistry, 2013 , vol. 52, # 9 p. 5260 - 5272

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被引用次数: 20

摘要

Systems formed using the VIVO2+ ion with tridentate ligands containing a (O, Narom, O) donor set were described. Examined ligands were 3, 5-bis (2-hydroxyphenyl)-1 H-1, 2, 4- triazole (H2hyphPh), 4-[3, 5-bis (2-hydroxyphenyl)-1, 2, 4-triazol-1-yl]-benzoic acid (H3hyphC), 4-[3, 5-bis (2-hydroxyphenyl)-1, 2, 4-triazol-1-yl]-sulfonic acid (H3hyphS), and 2, 6-bis (2′-hydroxyphenyl) pyridine (H2bhpp), with H3hyphC being an orally active iron ...