The Ritter Reaction of Tertiary Trihalomethylcarbinols and Related Substances

A Kaluszyner, S Blum…

文献索引：Kaluszyner,A. et al. Journal of Organic Chemistry, 1963 , vol. 28, p. 3588 - 3590

全文：HTML全文

被引用次数: 8

摘要

Then a plot of kinst us. k,nst [Cl-] should yield a straight line of slope k2/k3 and y-intercept k,. Instantaneous rate constants ob- tained from the slope of the curved "first-order" plots at several points were treated in this manner. Method B.-The substitution [Cl-] = c + r - [RCl] is made in eq. 2, where c is chloride concentration at a time taken as t = 0 and T is the concentration of substrate at t = 0. This equation may now be integrated to yield, after rearrangement