The Journal of Organic Chemistry

Reductive alkylation/arylation of arylcarbinols and ketones with organosilicon compounds

JA Cella

文献索引：Cella, J. A. Journal of Organic Chemistry, 1982 , vol. 47, # 11 p. 2125 - 2130

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被引用次数: 46

摘要

Arylcarbinols react with certain organosilanes in the presence of boron trifluoride to yield hydrocarbons resulting from transfer of an R group from silicon to carbon. The transfer works well with aryl-and allylsilanes and fails with alkylsilanes. Allylation of ionizable carbinols is sometimes accompanied by cation-mediated oligomerization. This can be offset by converting the carbinols in question to their respective allyldimethylsilyl ethers followed by ...