Bulletin of the Chemical Society of Japan

The Microwave Spectrum of trans-Ethylmethylsilane

M Hayashi, C Matsumura

文献索引：Hayashi,M.; Matsumura,C. Bulletin of the Chemical Society of Japan, 1972 , vol. 45, p. 732 - 735

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被引用次数: 36

摘要

The microwave spectra of CH 3 CH 2 SiH 2 CH 3 and CH 3 CH 2 SiD 2 CH 3 in the trans form were studied. The rotational constants calculated from the spectra can be explained satisfactorily with a model which has structural parameters transferred with only a slight modification, from the values reported for dimethylsilane and ethylsilane. From the observed splittings of the spectra, the barrier to the internal rotation of the SiCH 3 group was ...