The Journal of Organic Chemistry

Triply convergent, stereospecific alkene formation via Peterson olefination

AGM Barrett, JA Flygare

文献索引：Barrett, Anthony G. M.; Flygare, John A. Journal of Organic Chemistry, 1991 , vol. 56, # 2 p. 638 - 642

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被引用次数: 35

摘要

The Peterson olefination is the cumulative reaction of an a-silyl carbanion with a carbonyl compound to form a, &hydroxy silane, followed by elimination to yield the corresponding alkene.'The convergent formation of carbon-carbon double bonds is a reaction of fundamental importance in synthetic organic chemistry. Many related procedures, including the Wittig reaction, have been developed and used extensively for this purpose. Peterson ...