A New Selena??Aza??Payne??Type Rearrangement of Aziridinylmethyl Tosylates Mediated by Tetraselenotungstate

…, S Koutha, S Chandrasekaran

文献索引：Sureshkumar, Devarajulu; Koutha, Srinivasamurthy; Chandrasekaran, Srinivasan European Journal of Organic Chemistry, 2007 , # 27 p. 4543 - 4551

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被引用次数: 7

摘要

Abstract Tetraselenotungstate 1 reacts with simple (N-tosylaziridinyl) methyl tosylate derivatives to give allylamine derivatives as the only products by an unprecedented selena- aza-Payne-type rearrangement. When the methodology is extended to disubstituted (N- tosylaziridinyl) methyl tosylates, regio-and stereospecific ring-opening of the aziridines occurs to afford allylamine derivatives as the major products and cyclic five-membered ...