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The effect of polyether terminal chains in the liquid crystalline behavior of ortho-palladated complexes

…, J Buey, P Espinet, CE García-Prieto

文献索引:Baena; Buey; Espinet; Garcia-Prieto Journal of Organometallic Chemistry, 2005 , vol. 690, # 4 p. 998 - 1010

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被引用次数: 19

摘要

A series of benzylideneanilines bearing terminal polyether chains, HL (HL= R-C6H4–CHN– C6H4-R′: R= OC8H17, R′= O (CH2CH2O) 2C2H5; R= O (CH2CH2O) 2C2H5, R′= OC8H17; R= R′= O (CH2CH2O) 2C2H5; R= OC12H25, R′= O (CH2CH2O) 3C2H5; R= O (CH2CH2O) 3C2H5, R′= OC12H25; R= R′= O (CH2CH2O) 3C2H5) have been prepared. Their dinuclear,[Pd (μ-X) L] 2 (X= OAc, Cl, Br, SC8),[Pd2 (μ-SCn)(μ-X) L2](X= OAc, Cl; n= 8 ...