The Journal of organic chemistry

Indium (I) iodide-promoted cleavage of diaryl diselenides and disulfides and subsequent condensation with alkyl or acyl halides. One-pot efficient synthesis of …

BC Ranu, T Mandal

文献索引：Ranu, Brindaban C.; Mandal, Tanmay Journal of Organic Chemistry, 2004 , vol. 69, # 17 p. 5793 - 5795

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被引用次数: 132

摘要

Diphenyl diselenides and disulfides undergo facile cleavages by indium (I) iodide and the corresponding generated selenate and thiolate anions condense in situ with alkyl or acyl halides present in the reaction mixture. Thus, a simple, efficient, and general procedure has been developed for the synthesis of unsymmetrical diorganyl selenides, sulfides (thioethers), selenoesters, and thioesters by this one-pot reaction at room temperature.