2-Oxaspiranes and the Thorpe-Ingold Effect1, 2

S Searles, EF Lutz, M Tamres

文献索引：Searles,S. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 2932 - 2936

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被引用次数: 9

摘要

1 series of 2-oxaspiranes,(CH2),, C (CHz). i0 (I), with n= 2 (11), 3 (111), 4 (Is') and 5 (V), has been synthesized and studied to observe effects of small changes in bond angle deformation in the strained oxetane ring. Comparison was made of infrared spectra, hydrogen bonding abilities and ease of reductive cleavage with lithium aluminum hvdride of these compounds, as well as of oxetane (VI) and 3, 3-diethyloxetane (VII). The ...