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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Free-radical macrocyclization-transannular cyclization

NA Porter, VHT Chang, DR Magnin…

文献索引：Porter,N.A.; Chang,V.H.; Magnin,D.R. Journal of the American Chemical Society, 1988 , vol. 110, p. 3554

全文：HTML全文

被引用次数: 87

摘要

Abstract: Intramolecular free-radical addition to olefins substituted with electron-withdrawing groups has been studied. The free radicals are generated from the corresponding iodides by reaction with tributyltin hydride or tributyltin chloride/sodium cyanoborohydride. Macrocyclic compounds of 12-20 members are generated by this procedure in good yield, while endocyclization is favored, exocyclization can be forced if 1, l-dicyanesubstituted olefins ...

16-溴-1-十六烷醇结构式

16-溴-1-十六烷醇

~%

Cyclooctadecanone结构式

Cyclooctadecanone

16-bromohexadecanal结构式

16-bromohexadecanal

~%

Cyclooctadecanone结构式

Cyclooctadecanone

10-iododec-1-en-3-one结构式

10-iododec-1-en...

~15%

环癸酮结构式

3-癸酮结构式

dec-1-en-3-one结构式

详细

10-iododec-1-en-3-one结构式

10-iododec-1-en...

~0%

环癸酮结构式

3-癸酮结构式

dec-1-en-3-one结构式

详细

8-溴-1-辛醇结构式

~%

dec-1-en-3-one结构式

8-Bromooctanal结构式

~%

dec-1-en-3-one结构式

10-bromodec-1-en-3-ol结构式

10-bromodec-1-e...

~%

dec-1-en-3-one结构式

10-iododec-1-en-3-one结构式

10-iododec-1-en...

~0%

环癸酮结构式

3-癸酮结构式

dec-1-en-3-one结构式

详细

8-溴-1-辛醇结构式

~%

10-iododec-1-en-3-one结构式

10-iododec-1-en...

8-Bromooctanal结构式

~%

10-iododec-1-en-3-one结构式

10-iododec-1-en...

10-bromodec-1-en-3-ol结构式

10-bromodec-1-e...

~%

10-iododec-1-en-3-one结构式

10-iododec-1-en...

12-溴-1-十二烷醇结构式

12-溴-1-十二烷醇

~%

环十四烷-1-酮结构式

环十四烷-1-酮

12-bromododecanal结构式

12-bromododecanal

~%

环十四烷-1-酮结构式

环十四烷-1-酮

未登录结构式

~%

环十四烷-1-酮结构式

环十四烷-1-酮

14-bromo-1-tetradecen-3-one结构式

14-bromo-1-tetr...

~%

环十四烷-1-酮结构式

环十四烷-1-酮

14-iodo-1-tetradecen-3-one结构式

14-iodo-1-tetra...

~%

3-十四酮结构式

tetradec-1-en-3-one结构式

tetradec-1-en-3-one

环十四烷-1-酮结构式

环十四烷-1-酮

16-溴-1-十六烷醇结构式

16-溴-1-十六烷醇

~%

3-辛癸酮结构式

16-bromohexadecanal结构式

16-bromohexadecanal

~%

3-辛癸酮结构式

Photoinduced Electron Transfer Promoted Radical Ring Expansi...

[Nishikawa, Keisuke; Yoshimi, Yasuharu; Maeda, Kousuke; Morita, Toshio; Takahashi, Ichiro; Itou, Tatsuya; Inagaki, Sho; Hatanaka, Minoru Journal of Organic Chemistry, 2013 , vol. 78, # 2 p. 582 - 589]

Many-membered Carbon Rings. X. Reduction of Diametric Diketo...

[Blomquist et al. Journal of the American Chemical Society, 1955 , vol. 77, p. 1804]

Photoinduced Electron Transfer Promoted Radical Ring Expansi...

[Nishikawa, Keisuke; Yoshimi, Yasuharu; Maeda, Kousuke; Morita, Toshio; Takahashi, Ichiro; Itou, Tatsuya; Inagaki, Sho; Hatanaka, Minoru Journal of Organic Chemistry, 2013 , vol. 78, # 2 p. 582 - 589]

Photoinduced Electron Transfer Promoted Radical Ring Expansi...

[Nishikawa, Keisuke; Yoshimi, Yasuharu; Maeda, Kousuke; Morita, Toshio; Takahashi, Ichiro; Itou, Tatsuya; Inagaki, Sho; Hatanaka, Minoru Journal of Organic Chemistry, 2013 , vol. 78, # 2 p. 582 - 589]

Photoinduced Electron Transfer Promoted Radical Ring Expansi...

[Nishikawa, Keisuke; Yoshimi, Yasuharu; Maeda, Kousuke; Morita, Toshio; Takahashi, Ichiro; Itou, Tatsuya; Inagaki, Sho; Hatanaka, Minoru Journal of Organic Chemistry, 2013 , vol. 78, # 2 p. 582 - 589]