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Photoinduced Electron Transfer Promoted Radical Ring Expansion and Cyclization Reactions of α-(ω-Carboxyalkyl) β-Keto Esters

K Nishikawa, T Ando, K Maeda, T Morita…

文献索引:Nishikawa, Keisuke; Yoshimi, Yasuharu; Maeda, Kousuke; Morita, Toshio; Takahashi, Ichiro; Itou, Tatsuya; Inagaki, Sho; Hatanaka, Minoru Journal of Organic Chemistry, 2013 , vol. 78, # 2 p. 582 - 589

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被引用次数: 13

摘要

Photoinduced electron transfer (PET) promoted decarboxylation of α-(ω-carboxyalkyl) β-keto esters undergoes radical ring expansion and cyclization reactions. This mild and environmentally friendly method can provide one-carbon expanded γ-keto esters and bicyclic alcohols, and the product distribution is strongly dependent on the length of the alkyl chain containing the terminal carboxylate group.