The Journal of organic chemistry

Palladium-catalyzed thiocarbonylation of iodoarenes with thiols in phosphonium salt ionic liquids

H Cao, L McNamee, H Alper

文献索引：Cao, Hong; McNamee, Laura; Alper, Howard Journal of Organic Chemistry, 2008 , vol. 73, # 9 p. 3530 - 3534

被引用次数: 78

摘要

Trihexyl (tetradecyl) phosphonium hexafluorophosphate, a phosphonium salt ionic liquid (PSIL) is a particularly effective general reaction media for the Pd-catalyzed carbonylation reaction of iodoarenes and thiols to form thioesters. Recycling of the ionic liquid containing active Pd-catalyst was also demonstrated.

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