Air-Stable, Cationic, Lewis Acid, Titanocene Perfluorooctanesulfonate–Catalyzed Reductive Cleavage of S–S Bond by Zinc and Its Application in Synthesis of …

…, XH Xu, YH Li, LL Shao, GP Zhang…

文献索引：Qiu, Ren Hua; Xu, Xin Hua; Li, Yin Hui; Shao, Ling Ling; Zhang, Guo Ping; An, De Lie Synthetic Communications, 2010 , vol. 40, # 22 p. 3309 - 3314

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被引用次数: 4

摘要

Titanocene perfluorooctanesulfonate is air-stable complex. In the presence of 10 mol% of the complex, reductive cleavage of an S–S bond by zinc in commercial tetrahydrofuran at room temperature led to nucleophilic sulfur anion species, which reacted with acid anhydrides to afford thioesters in good to excellent yields.