Syntheses and structures of N'-(5-bromo-2-hydroxybenzylidene)-4-methoxybenzohydrazide and its dioxomolybdenum (VI) complex with catalytic epoxidation property
A new Schiff base N′-(5-bromo-2-hydroxybenzylidene)-4-methoxybenzohydrazide (H2BMH) and its dioxomolybdenum (VI) complex [MoO2 (BMH)(EtOH)] have been synthesized and characterized by elemental analysis, IR spectra, and single crystal X-ray determination. The Schiff base crystallized in the orthorhombic space group P 212121 and the complex crystallized in the triclinic space group. The Schiff base coordinates to Mo ...