Syntheses and structures of N'-(5-bromo-2-hydroxybenzylidene)-4-methoxybenzohydrazide and its dioxomolybdenum (VI) complex with catalytic epoxidation property

…, Y Wang, YJ Cai, XJ Long, W Chen

Index: Cui, Yong-Ming; Wang, Yan; Cai, Ying-Jie; Long, Xue-Jun; Chen, Wu Journal of Coordination Chemistry, 2013 , vol. 66, # 13 p. 2325 - 2334

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Abstract

A new Schiff base N′-(5-bromo-2-hydroxybenzylidene)-4-methoxybenzohydrazide (H2BMH) and its dioxomolybdenum (VI) complex [MoO2 (BMH)(EtOH)] have been synthesized and characterized by elemental analysis, IR spectra, and single crystal X-ray determination. The Schiff base crystallized in the orthorhombic space group P 212121 and the complex crystallized in the triclinic space group. The Schiff base coordinates to Mo ...