Formation of Phosphate Derivatives by the Reaction of Propyl and Allyl Halides with Phosphorus Trichloride and Oxygen

Y Okamoto, T Okada, H Sakurai

文献索引：Okamoto,Y. et al. Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 484 - 487

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被引用次数: 6

摘要

In addition to phosphonyl dichlorides, a significant amount of phosphoryl dichlorides was obtained by the reaction of propyl and allyl halides with phosphorus trichloride in oxygen atmosphere. Formation of the P–O–C bond can be explained by a scheme involving a preferential reaction of the bridged intermediate radical with oxygen.